Actually, the two "burnable" layers are on the same side of the disc. Illustration here: http://www.dvdrw.com/press/duallayer.htm
Single layer= 4.7GB Dual layer= 8.5GB Use a program like DVDShrink to compress DVD video to fit on single layer media... http://www.mrbass.org/dvdshrink/ If Shrink can't rip it, then rip it to your HD first with DVDFab Decrypter... http://dvdidle.com/free.htm There's also a guide on how to use DVDShrink at the first link... Both programs are free!!!